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dc.contributor.advisorŠpirko, Vladimír
dc.creatorŠedivcová, Tereza
dc.date.accessioned2018-04-12T12:38:10Z
dc.date.available2018-04-12T12:38:10Z
dc.date.issued2007
dc.identifier.urihttp://hdl.handle.net/20.500.11956/95726
dc.description.abstractAlÉa High]y cmrdated i*{nCI ratfuttir ere 'p| to calculaÍr the potentia] en- erry and spin-ortÉt cryEag fuctils fu wll ď tbe laest electronic states of the Co2+ dicatiou. Usint ttF fEí{iE tb pcitis err| |ifutimes of the correspond. ing vibrmic states are e|v.b.léd b1r mx gf }6fo *abiišation and complex-scaling methods Yithin tb€ baclut ď mhicLrnr| seródfru8€Í anal;'sis. Since the pre- dicted |ifuimes agrt€ xtr ritl tb -.rye Er'tes. fi-tb' the same plocedure based oD the a} t'dr.a calcÚI'tis c.D be rrd to kmiuáte the pcitions and widths of tbe isodatrmic sýst€D (sP+. Tbe mptcd E&tim€s ď serrcral vibronic states of CS2+ are il the rao6e l 1s < l < 1ps. tba&e tb€se stát€s goren the second step in the seqrntial Fthfq cs. . S- + Cý* .- S+ + C+ + S+ of the overal1 three-body CooM e4tr*n ďq. In terc ď the ftre6riry erqhrix' an att€mpt to determine both Vis arrd IR emissiln and e.kÉln q*e ď CtF* is made. Radiative lifetimes found for transition mmoú E'11ir.lft* rť| FlnétF:n A co€frdents are eva'l'uated using the compla-scaling ď li!fu&ly. j}6 mi<i61 is mncernď, the radiative ]ifetimes ď AsDř .-t ďtr &ctrb *at€s in Cď+ are longer than the rate of pledissociatin frm -r".+ sta€s" thth lmlÉit impossible íor emission to occur. The absorptin ryectn ď A'Dts .- x3tr 'rr{ bru .-- aIE+ are determined and their abso]ute...en_US
dc.description.abstractAlÉa High]y cmrdated i*{nCI ratfuttir ere 'p| to calculaÍr the potentia] en- erry and spin-ortÉt cryEag fuctils fu wll ď tbe laest electronic states of the Co2+ dicatiou. Usint ttF fEí{iE tb pcitis err| |ifutimes of the correspond. ing vibrmic states are e|v.b.léd b1r mx gf }6fo *abiišation and complex-scaling methods Yithin tb€ baclut ď mhicLrnr| seródfru8€Í anal;'sis. Since the pre- dicted |ifuimes agrt€ xtr ritl tb -.rye Er'tes. fi-tb' the same plocedure based oD the a} t'dr.a calcÚI'tis c.D be rrd to kmiuáte the pcitions and widths of tbe isodatrmic sýst€D (sP+. Tbe mptcd E&tim€s ď serrcral vibronic states of CS2+ are il the rao6e l 1s < l < 1ps. tba&e tb€se stát€s goren the second step in the seqrntial Fthfq cs. . S- + Cý* .- S+ + C+ + S+ of the overal1 three-body CooM e4tr*n ďq. In terc ď the ftre6riry erqhrix' an att€mpt to determine both Vis arrd IR emissiln and e.kÉln q*e ď CtF* is made. Radiative lifetimes found for transition mmoú E'11ir.lft* rť| FlnétF:n A co€frdents are eva'l'uated using the compla-scaling ď li!fu&ly. j}6 mi<i61 is mncernď, the radiative ]ifetimes ď AsDř .-t ďtr &ctrb *at€s in Cď+ are longer than the rate of pledissociatin frm -r".+ sta€s" thth lmlÉit impossible íor emission to occur. The absorptin ryectn ď A'Dts .- x3tr 'rr{ bru .-- aIE+ are determined and their abso]ute...cs_CZ
dc.languageEnglishcs_CZ
dc.language.isoen_US
dc.publisherUniverzita Karlova, Přírodovědecká fakultacs_CZ
dc.titleProperties of metastable states of small dicationsen_US
dc.typedizertační prácecs_CZ
dcterms.created2007
dcterms.dateAccepted2007-03-15
dc.description.departmentDepartment of Physical and Macromolecular Chemistryen_US
dc.description.departmentKatedra fyzikální a makromol. chemiecs_CZ
dc.description.facultyFaculty of Scienceen_US
dc.description.facultyPřírodovědecká fakultacs_CZ
dc.identifier.repId112794
dc.contributor.refereeSkála, Lubomír
dc.contributor.refereeUrban, Ján
dc.identifier.aleph000581320
thesis.degree.namePh.D.
thesis.degree.leveldoktorskécs_CZ
thesis.degree.discipline-en_US
thesis.degree.discipline-cs_CZ
thesis.degree.programFyzikální chemiecs_CZ
thesis.degree.programPhysical Chemistryen_US
uk.thesis.typedizertační prácecs_CZ
uk.taxonomy.organization-csPřírodovědecká fakulta::Katedra fyzikální a makromol. chemiecs_CZ
uk.taxonomy.organization-enFaculty of Science::Department of Physical and Macromolecular Chemistryen_US
uk.faculty-name.csPřírodovědecká fakultacs_CZ
uk.faculty-name.enFaculty of Scienceen_US
uk.faculty-abbr.csPřFcs_CZ
uk.degree-discipline.cs-cs_CZ
uk.degree-discipline.en-en_US
uk.degree-program.csFyzikální chemiecs_CZ
uk.degree-program.enPhysical Chemistryen_US
thesis.grade.csProspělcs_CZ
thesis.grade.enPassen_US
uk.abstract.csAlÉa High]y cmrdated i*{nCI ratfuttir ere 'p| to calculaÍr the potentia] en- erry and spin-ortÉt cryEag fuctils fu wll ď tbe laest electronic states of the Co2+ dicatiou. Usint ttF fEí{iE tb pcitis err| |ifutimes of the correspond. ing vibrmic states are e|v.b.léd b1r mx gf }6fo *abiišation and complex-scaling methods Yithin tb€ baclut ď mhicLrnr| seródfru8€Í anal;'sis. Since the pre- dicted |ifuimes agrt€ xtr ritl tb -.rye Er'tes. fi-tb' the same plocedure based oD the a} t'dr.a calcÚI'tis c.D be rrd to kmiuáte the pcitions and widths of tbe isodatrmic sýst€D (sP+. Tbe mptcd E&tim€s ď serrcral vibronic states of CS2+ are il the rao6e l 1s < l < 1ps. tba&e tb€se stát€s goren the second step in the seqrntial Fthfq cs. . S- + Cý* .- S+ + C+ + S+ of the overal1 three-body CooM e4tr*n ďq. In terc ď the ftre6riry erqhrix' an att€mpt to determine both Vis arrd IR emissiln and e.kÉln q*e ď CtF* is made. Radiative lifetimes found for transition mmoú E'11ir.lft* rť| FlnétF:n A co€frdents are eva'l'uated using the compla-scaling ď li!fu&ly. j}6 mi<i61 is mncernď, the radiative ]ifetimes ď AsDř .-t ďtr &ctrb *at€s in Cď+ are longer than the rate of pledissociatin frm -r".+ sta€s" thth lmlÉit impossible íor emission to occur. The absorptin ryectn ď A'Dts .- x3tr 'rr{ bru .-- aIE+ are determined and their abso]ute...cs_CZ
uk.abstract.enAlÉa High]y cmrdated i*{nCI ratfuttir ere 'p| to calculaÍr the potentia] en- erry and spin-ortÉt cryEag fuctils fu wll ď tbe laest electronic states of the Co2+ dicatiou. Usint ttF fEí{iE tb pcitis err| |ifutimes of the correspond. ing vibrmic states are e|v.b.léd b1r mx gf }6fo *abiišation and complex-scaling methods Yithin tb€ baclut ď mhicLrnr| seródfru8€Í anal;'sis. Since the pre- dicted |ifuimes agrt€ xtr ritl tb -.rye Er'tes. fi-tb' the same plocedure based oD the a} t'dr.a calcÚI'tis c.D be rrd to kmiuáte the pcitions and widths of tbe isodatrmic sýst€D (sP+. Tbe mptcd E&tim€s ď serrcral vibronic states of CS2+ are il the rao6e l 1s < l < 1ps. tba&e tb€se stát€s goren the second step in the seqrntial Fthfq cs. . S- + Cý* .- S+ + C+ + S+ of the overal1 three-body CooM e4tr*n ďq. In terc ď the ftre6riry erqhrix' an att€mpt to determine both Vis arrd IR emissiln and e.kÉln q*e ď CtF* is made. Radiative lifetimes found for transition mmoú E'11ir.lft* rť| FlnétF:n A co€frdents are eva'l'uated using the compla-scaling ď li!fu&ly. j}6 mi<i61 is mncernď, the radiative ]ifetimes ď AsDř .-t ďtr &ctrb *at€s in Cď+ are longer than the rate of pledissociatin frm -r".+ sta€s" thth lmlÉit impossible íor emission to occur. The absorptin ryectn ď A'Dts .- x3tr 'rr{ bru .-- aIE+ are determined and their abso]ute...en_US
uk.file-availabilityV
uk.publication.placePrahacs_CZ
uk.grantorUniverzita Karlova, Přírodovědecká fakulta, Katedra fyzikální a makromol. chemiecs_CZ
dc.identifier.lisID990005813200106986


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