dc.contributor.advisor | Špirko, Vladimír | |
dc.creator | Šedivcová, Tereza | |
dc.date.accessioned | 2018-04-12T12:38:10Z | |
dc.date.available | 2018-04-12T12:38:10Z | |
dc.date.issued | 2007 | |
dc.identifier.uri | http://hdl.handle.net/20.500.11956/95726 | |
dc.description.abstract | AlÉa High]y cmrdated i*{nCI ratfuttir ere 'p| to calculaÍr the potentia] en- erry and spin-ortÉt cryEag fuctils fu wll ď tbe laest electronic states of the Co2+ dicatiou. Usint ttF fEí{iE tb pcitis err| |ifutimes of the correspond. ing vibrmic states are e|v.b.léd b1r mx gf }6fo *abiišation and complex-scaling methods Yithin tb€ baclut ď mhicLrnr| seródfru8€Í anal;'sis. Since the pre- dicted |ifuimes agrt€ xtr ritl tb -.rye Er'tes. fi-tb' the same plocedure based oD the a} t'dr.a calcÚI'tis c.D be rrd to kmiuáte the pcitions and widths of tbe isodatrmic sýst€D (sP+. Tbe mptcd E&tim€s ď serrcral vibronic states of CS2+ are il the rao6e l 1s < l < 1ps. tba&e tb€se stát€s goren the second step in the seqrntial Fthfq cs. . S- + Cý* .- S+ + C+ + S+ of the overal1 three-body CooM e4tr*n ďq. In terc ď the ftre6riry erqhrix' an att€mpt to determine both Vis arrd IR emissiln and e.kÉln q*e ď CtF* is made. Radiative lifetimes found for transition mmoú E'11ir.lft* rť| FlnétF:n A co€frdents are eva'l'uated using the compla-scaling ď li!fu&ly. j}6 mi<i61 is mncernď, the radiative ]ifetimes ď AsDř .-t ďtr &ctrb *at€s in Cď+ are longer than the rate of pledissociatin frm -r".+ sta€s" thth lmlÉit impossible íor emission to occur. The absorptin ryectn ď A'Dts .- x3tr 'rr{ bru .-- aIE+ are determined and their abso]ute... | en_US |
dc.description.abstract | AlÉa High]y cmrdated i*{nCI ratfuttir ere 'p| to calculaÍr the potentia] en- erry and spin-ortÉt cryEag fuctils fu wll ď tbe laest electronic states of the Co2+ dicatiou. Usint ttF fEí{iE tb pcitis err| |ifutimes of the correspond. ing vibrmic states are e|v.b.léd b1r mx gf }6fo *abiišation and complex-scaling methods Yithin tb€ baclut ď mhicLrnr| seródfru8€Í anal;'sis. Since the pre- dicted |ifuimes agrt€ xtr ritl tb -.rye Er'tes. fi-tb' the same plocedure based oD the a} t'dr.a calcÚI'tis c.D be rrd to kmiuáte the pcitions and widths of tbe isodatrmic sýst€D (sP+. Tbe mptcd E&tim€s ď serrcral vibronic states of CS2+ are il the rao6e l 1s < l < 1ps. tba&e tb€se stát€s goren the second step in the seqrntial Fthfq cs. . S- + Cý* .- S+ + C+ + S+ of the overal1 three-body CooM e4tr*n ďq. In terc ď the ftre6riry erqhrix' an att€mpt to determine both Vis arrd IR emissiln and e.kÉln q*e ď CtF* is made. Radiative lifetimes found for transition mmoú E'11ir.lft* rť| FlnétF:n A co€frdents are eva'l'uated using the compla-scaling ď li!fu&ly. j}6 mi<i61 is mncernď, the radiative ]ifetimes ď AsDř .-t ďtr &ctrb *at€s in Cď+ are longer than the rate of pledissociatin frm -r".+ sta€s" thth lmlÉit impossible íor emission to occur. The absorptin ryectn ď A'Dts .- x3tr 'rr{ bru .-- aIE+ are determined and their abso]ute... | cs_CZ |
dc.language | English | cs_CZ |
dc.language.iso | en_US | |
dc.publisher | Univerzita Karlova, Přírodovědecká fakulta | cs_CZ |
dc.title | Properties of metastable states of small dications | en_US |
dc.type | dizertační práce | cs_CZ |
dcterms.created | 2007 | |
dcterms.dateAccepted | 2007-03-15 | |
dc.description.department | Department of Physical and Macromolecular Chemistry | en_US |
dc.description.department | Katedra fyzikální a makromol. chemie | cs_CZ |
dc.description.faculty | Faculty of Science | en_US |
dc.description.faculty | Přírodovědecká fakulta | cs_CZ |
dc.identifier.repId | 112794 | |
dc.contributor.referee | Skála, Lubomír | |
dc.contributor.referee | Urban, Ján | |
dc.identifier.aleph | 000581320 | |
thesis.degree.name | Ph.D. | |
thesis.degree.level | doktorské | cs_CZ |
thesis.degree.discipline | - | en_US |
thesis.degree.discipline | - | cs_CZ |
thesis.degree.program | Fyzikální chemie | cs_CZ |
thesis.degree.program | Physical Chemistry | en_US |
uk.thesis.type | dizertační práce | cs_CZ |
uk.taxonomy.organization-cs | Přírodovědecká fakulta::Katedra fyzikální a makromol. chemie | cs_CZ |
uk.taxonomy.organization-en | Faculty of Science::Department of Physical and Macromolecular Chemistry | en_US |
uk.faculty-name.cs | Přírodovědecká fakulta | cs_CZ |
uk.faculty-name.en | Faculty of Science | en_US |
uk.faculty-abbr.cs | PřF | cs_CZ |
uk.degree-discipline.cs | - | cs_CZ |
uk.degree-discipline.en | - | en_US |
uk.degree-program.cs | Fyzikální chemie | cs_CZ |
uk.degree-program.en | Physical Chemistry | en_US |
thesis.grade.cs | Prospěl | cs_CZ |
thesis.grade.en | Pass | en_US |
uk.abstract.cs | AlÉa High]y cmrdated i*{nCI ratfuttir ere 'p| to calculaÍr the potentia] en- erry and spin-ortÉt cryEag fuctils fu wll ď tbe laest electronic states of the Co2+ dicatiou. Usint ttF fEí{iE tb pcitis err| |ifutimes of the correspond. ing vibrmic states are e|v.b.léd b1r mx gf }6fo *abiišation and complex-scaling methods Yithin tb€ baclut ď mhicLrnr| seródfru8€Í anal;'sis. Since the pre- dicted |ifuimes agrt€ xtr ritl tb -.rye Er'tes. fi-tb' the same plocedure based oD the a} t'dr.a calcÚI'tis c.D be rrd to kmiuáte the pcitions and widths of tbe isodatrmic sýst€D (sP+. Tbe mptcd E&tim€s ď serrcral vibronic states of CS2+ are il the rao6e l 1s < l < 1ps. tba&e tb€se stát€s goren the second step in the seqrntial Fthfq cs. . S- + Cý* .- S+ + C+ + S+ of the overal1 three-body CooM e4tr*n ďq. In terc ď the ftre6riry erqhrix' an att€mpt to determine both Vis arrd IR emissiln and e.kÉln q*e ď CtF* is made. Radiative lifetimes found for transition mmoú E'11ir.lft* rť| FlnétF:n A co€frdents are eva'l'uated using the compla-scaling ď li!fu&ly. j}6 mi<i61 is mncernď, the radiative ]ifetimes ď AsDř .-t ďtr &ctrb *at€s in Cď+ are longer than the rate of pledissociatin frm -r".+ sta€s" thth lmlÉit impossible íor emission to occur. The absorptin ryectn ď A'Dts .- x3tr 'rr{ bru .-- aIE+ are determined and their abso]ute... | cs_CZ |
uk.abstract.en | AlÉa High]y cmrdated i*{nCI ratfuttir ere 'p| to calculaÍr the potentia] en- erry and spin-ortÉt cryEag fuctils fu wll ď tbe laest electronic states of the Co2+ dicatiou. Usint ttF fEí{iE tb pcitis err| |ifutimes of the correspond. ing vibrmic states are e|v.b.léd b1r mx gf }6fo *abiišation and complex-scaling methods Yithin tb€ baclut ď mhicLrnr| seródfru8€Í anal;'sis. Since the pre- dicted |ifuimes agrt€ xtr ritl tb -.rye Er'tes. fi-tb' the same plocedure based oD the a} t'dr.a calcÚI'tis c.D be rrd to kmiuáte the pcitions and widths of tbe isodatrmic sýst€D (sP+. Tbe mptcd E&tim€s ď serrcral vibronic states of CS2+ are il the rao6e l 1s < l < 1ps. tba&e tb€se stát€s goren the second step in the seqrntial Fthfq cs. . S- + Cý* .- S+ + C+ + S+ of the overal1 three-body CooM e4tr*n ďq. In terc ď the ftre6riry erqhrix' an att€mpt to determine both Vis arrd IR emissiln and e.kÉln q*e ď CtF* is made. Radiative lifetimes found for transition mmoú E'11ir.lft* rť| FlnétF:n A co€frdents are eva'l'uated using the compla-scaling ď li!fu&ly. j}6 mi<i61 is mncernď, the radiative ]ifetimes ď AsDř .-t ďtr &ctrb *at€s in Cď+ are longer than the rate of pledissociatin frm -r".+ sta€s" thth lmlÉit impossible íor emission to occur. The absorptin ryectn ď A'Dts .- x3tr 'rr{ bru .-- aIE+ are determined and their abso]ute... | en_US |
uk.file-availability | V | |
uk.publication.place | Praha | cs_CZ |
uk.grantor | Univerzita Karlova, Přírodovědecká fakulta, Katedra fyzikální a makromol. chemie | cs_CZ |
dc.identifier.lisID | 990005813200106986 | |